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- W2107229095 abstract "Optically active 1-alkoxy- and 1-amino-3-phospholene oxides were synthesized by the reaction of the corresponding 1-chloro-3-phospholene oxides with (1R,2S,5R)-(–)menthol and (S)-(–)-α-phenylethylamine. The 3-methyl-3-phospholene oxides were subjected to dichlorocyclopropanation under liquid–liquid phase transfer catalytic conditions to afford the 3-phosphabicyclo[3.1.0]hexane 3-oxides as a mixture of four diastereomers. Thermolysis of the menthyl-phosphabicyclohexane oxides led to the corresponding 1,2-dihydrophosphinine oxide as a diastereomeric mixture of two double-bond isomers. As a result of additional steps, the dichlorocarbene addition reaction of the 1-menthyl-3,4-dimethyl-3-phospholene oxide resulted in eventually, the formation of a 4-dichloromethylene-1,4-dihydrophosphinine oxide. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:271–277, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20599" @default.
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- W2107229095 date "2010-01-01" @default.
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- W2107229095 title "The synthesis of optically active P-heterocycles" @default.
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