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- W2107241792 abstract "The reaction of lithium tetrahydroaluminate with chloropentafluorobenzene yields mainly p-chlorotetrafluorobenzene. The nature of the solvent influences the formation of other fluorocarbon compounds in the reaction. p-Chlorotetrafluoro-benzene reacts further with LiAlH4 in tetrahydrofuran, but not in diethyl ether, to give predominantly 1-chloro-2,3,5-trifluorobenzene and 1-chloro-2,3,6- trifluorobenzene. In turn, the trifluorobenzene compounds react with LiAlH4 in tetrahydrofuran to give mainly 1-chloro-2,5-difluorobenzene. The major products are formed by a combination of (i) direct nucleophilic displacement of fluorine in the chloropolyfluorobenzene compounds by hydride, and (ii) hydrolysis of the compounds LiAl(C6F4Cl)H2F, LiAl(C6F3HCl)H2F, and LiAl(C6F2H2Cl)H2F. The fluorocarbon- aluminium compounds have not been isolated from solution but they were characterized by quantitative determination of the products of hydrolysis and by 1H and 19F N.M.R. spectroscopy." @default.
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- W2107241792 date "1973-01-01" @default.
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- W2107241792 title "Fluorocarbon-aluminium compounds. IV. Reactions of some chloropolyfluorobenzenes with lithium tetrahydroaluminate" @default.
- W2107241792 cites W640694092 @default.
- W2107241792 doi "https://doi.org/10.1071/ch9730063" @default.
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