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• W2107254623 endingPage "10411" @default.
• W2107254623 startingPage "10408" @default.
• W2107254623 abstract "Abstract Common wisdom has it that organoboranes are readily oxidized. Described herein is that also their reduction can result in remarkable chemistry. Treatment of dimeric 9H‐9‐borafluorene with Li metal in toluene yields two strikingly different classes of compounds. One part of the sample reacts in a way similar to B 2 H 6 , thus affording an aryl(hydro)borane cluster reminiscent of the [B 3 H 8 ] − anion. The other part furnishes a dianionic boron‐doped graphene flake devoid of hydrogen substituents at the boron centers and featuring a central BB bond. A change in the solvent to THF allows an isolation of this dibenzo[g,p]chrysene analogue in good yields." @default.
• W2107254623 created "2016-06-24" @default.
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• W2107254623 creator A5062267065 @default.
• W2107254623 date "2014-08-11" @default.
• W2107254623 modified "2023-10-18" @default.
• W2107254623 title "Extensive Structural Rearrangements upon Reduction of 9<i>H</i>-9-Borafluorene" @default.
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• W2107254623 doi "https://doi.org/10.1002/anie.201405957" @default.
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