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- W2107257621 abstract "Reaction of bis(triphenylphosphine)bis(chloro)-nitrido-rhenium(V) with two equivalents of 2-aminothiophenol results in the formation of a neutral, diamagnetic phosphorane thioiminato complex, Re(V)(NPPh 3 )(2-amino- thiophenolato) 2 , for which the X-ray crystal structure is reported. The compound crystallizes in the monoclinic, P 2 1 / c space group with a =12.938(4), b = 21.091(7), c = 11.578(4) A and β= 102.71(3)°. The nucleophilic attack by the free triphenylphosphine ligand onto the nitrido group is rather unusual. Therefore the neutral oxo complex, Re(V)O(2-aminothiophenolato)2, where one amino group is deprotonated, was synthesized and investigated for its reactivity towards nucleophilic attack by triphenylphosphine. This complex was found to have little such reactivity." @default.
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- W2107257621 date "1993-09-01" @default.
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- W2107257621 title "The ligand exchange reaction between Re(V)NCl2(PPh3)2 and 2-aminothiophenol: formation of a neutral Re(V) phosphorane thioiminato complex" @default.
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- W2107257621 doi "https://doi.org/10.1016/s0020-1693(00)82838-8" @default.
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