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- W2107264513 abstract "Abstract Treatment of allylic alcohols with hexafluoropropene-diethylamine adduct (PPDA) afforded N,N-diethyl-2-fluoro-2-trifluoromethyl-4-alkenamides which were formed by the Claisen rearrangement of intermediary 2-alkenyl-1-diethylamino-2,3,3,3-tetrafluoro-1-propenyl ethers. Although (E)-allylic alcohols gave two diastereomeric products in about 1:1 ratio, (Z)-allylic alcohols gave the corresponding product as a single diastereomer." @default.
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- W2107264513 date "2004-03-09" @default.
- W2107264513 modified "2023-09-27" @default.
- W2107264513 title "A Novel Reaction of Allylic Alcohols with Hexafluoropropene-Diethylamine Adduct (PPDA) to Form 2-Fluoro-2-trifluoromethyl-4-alkenamide." @default.
- W2107264513 cites W2951023360 @default.
- W2107264513 doi "https://doi.org/10.1002/chin.200410088" @default.
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