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• W2107372017 abstract "Electrophilic terminal phosphinidene complexes [Ar-Ar-P-W(CO)5] (Ar-Ar: biaryl or an analogue thereof) undergo a spontaneous insertion of the phosphorus atom into the vicinal CH bonds to give annelated phospholes. Twelve examples are described, including biphenyl, thienyl, pyrrolyl, and benzofuryl groups as biaryl moieties. The activation energy of the insertion reaction is quite low (about 2 kcal mol−1)." @default.
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• W2107372017 date "2014-12-09" @default.
• W2107372017 modified "2023-10-06" @default.
• W2107372017 title "Synthesis of Annelated Phospholes through Intramolecular CH Activation by Monovalent Phosphorus" @default.
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• W2107372017 doi "https://doi.org/10.1002/anie.201410603" @default.
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