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- W2107401979 abstract "The growth of glycine film by thermal evaporation on Si(111)7×7 at room temperature has been studied by X-ray photoemission. In contrast to common carboxylic acids, glycine is found to adsorb on Si(111)7×7 dissociatively through cleavage of a N–H bond instead of O–H bond. The intricate evolution of the observed N 1s features at 399.1, 401.4, and 402.2 eV with increasing film thickness demonstrates the existence of a transitional adlayer between the first adlayer and the zwitterionic multilayer. This transitional adlayer is estimated to be 1–2 adlayer thick and is characterized by the presence of intermolecular N⋯HO hydrogen bond. An intramolecular proton transfer mechanism is proposed to account for the adsorption process through the amino group." @default.
- W2107401979 created "2016-06-24" @default.
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- W2107401979 date "2009-03-28" @default.
- W2107401979 modified "2023-09-29" @default.
- W2107401979 title "Hydrogen-bond mediated transitional adlayer of glycine on Si(111)7×7 at room temperature" @default.
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- W2107401979 doi "https://doi.org/10.1063/1.3106762" @default.
- W2107401979 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19334801" @default.
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