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- W2107579711 abstract "Thiol−olefin co-oxygenation (TOCO) of substituted allylic alcohols generates α-hydroxyperoxides that can be condensed in situ with various ketones to afford a series of functionalized 1,2,4-trioxanes in good yields. Manipulation of the phenylsulfenyl group in 4a allows for convenient modification to the spiro-trioxane substituents, and we describe, for the first time, the preparation of a new class of antimalarial prodrug." @default.
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- W2107579711 date "2004-07-28" @default.
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- W2107579711 title "Application of Thiol−Olefin Co-oxygenation Methodology to a New Synthesis of the 1,2,4-Trioxane Pharmacophore" @default.
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- W2107579711 doi "https://doi.org/10.1021/ol0492142" @default.
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