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- W2107601091 abstract "A cyclic phosphaallyl anion generated from a phosphorus-carbon triple bond (phosphaalkyne) was allowed to react with dimethyl- and di-p-tolyl disulfide to afford the corresponding 1,3-diphosphacyclobutane-2,4-diyls bearing the sulfanyl substituent on phosphorus. The sulfanyl-bearing P-heterocyclic biradicals showed high stability permitting easy handling under ambient conditions. UV-vis spectra and electrochemical properties of the compounds indicated that the sulfanyl groups behave as electron-withdrawing groups to affect electronic properties of the cyclic biradical moiety. X-ray analysis of the p-tolylsulfanyl derivative indicated that the sulfanyl group causes no significant modification in the metric parameters around the central 4-membred biradical skeleton." @default.
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- W2107601091 date "2010-08-01" @default.
- W2107601091 modified "2023-09-26" @default.
- W2107601091 title "Synthesis and physicochemical properties of stable 1,3-diphosphacyclobutane-2,4-diyls bearing sulfanyl groups" @default.
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- W2107601091 doi "https://doi.org/10.1016/j.crci.2010.04.007" @default.
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