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- W2107732406 abstract "The preparation of cis-[Os(NH3)4(CO)2]X2 (X = Cl, Br, I) by reaction of cis- tetrahalodicarbonylosmate(II) with liquid NH3 in the supercritical range at 170°C and of fac-[Os(NH3)3(CO)3]X2 by reaction of fac-trihalotricarbonylosmate(II) with liquid NH3, at room temperature is described for the first time. The amminecarbonylosmium(II) complexes are extraordinarily stable and are attacked neither by Cl2Br2 nor hot hydrogen halides. The new compounds are characterized by their vibrational and UV-spectra. Es wird über die erstmalige Darstellung von cis-[Os(NH3)4(CO)2]X2 (X = Cl, Br, J) durch Umsetzung von cis-Tetrahalogenodicarbonylosmat(II) mit flüss. NH3 im überkritischen Bereich bei 170°C und von fac-[Os(NH3)3(CO)3]X2 durch Behandeln von fac-Trihalogenotricarbonylosmat(II) mit flüss. NH3 bei Raumtemperatur berichtet. Die Ammincarbonylosmium(II)-Komplexe sind ausser ordentlich stabil und werden von Cl2 und Br2 noch von heissen Halogenwasserstoffsäuren angegriffen. Die neuen Verbindungen werden durch ihre Schwingungs- und UV- Spektren charakterisiert." @default.
- W2107732406 created "2016-06-24" @default.
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- W2107732406 date "1978-02-01" @default.
- W2107732406 modified "2023-09-24" @default.
- W2107732406 title "Darstellung von cis-tetrammindicarbonyl- und fac-triammintricarbonylosmium(II)-halogeniden" @default.
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- W2107732406 doi "https://doi.org/10.1016/s0022-328x(00)88756-2" @default.
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