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- W2107766013 abstract "The oxidation of (-)-tabersonine (1) with dimethyldioxirane (DMD) in neutral and acidic medium gave 16-hydroxytabersonine-N-oxide (3) and the didehydrovincamine isomers 4 and 5, respectively. (+)-14,15-Didehydro-quebrachamine (7) furnished the hydroxyindolenine 9, and the pentacyclic derivative 11. (+)-Quebrachamine (8) and DMD in neutral medium gave (7S,20S)-(+)-rhazidigenine (12) which was converted to (2R,7S,20S)-(+)-rhazidine (13b) with hydrochloric acid." @default.
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- W2107766013 date "2002-07-01" @default.
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- W2107766013 title "Synthesis of vinca alakaloids and realated compounds<b>98</b>. Oxidation with dimethyldioxirane of compounds containing the aspidospermane and quebrachamine ring system. A simple synthesis of (7<i>S</i>,20<i>S</i>)-(+)-rhazidigenine and (2<i>R</i>,7<i>S</i>,20<i>S</i>)-(+)-rhazidine" @default.
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- W2107766013 doi "https://doi.org/10.1002/jhet.5570390423" @default.
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