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- W2107792634 abstract "Abstract Two novel lanthanide metal coordination frameworks were synthesized by reaction of 1 H ‐benzimidazole‐5‐carboxylic acid (H 2 bic) in the presence of the coligand oxalate with lanthanide ions under hydrothermal conditions, namely, [Eu(H 2 bic)(C 2 O 4 ) 1.5 ] · H 2 O ( 1 ) and [La(H 2 bic)(C 2 O 4 ) 1.5 ] · H 2 O ( 2 ). The two compounds 1 and 2 are isomorphous and have a 2D layer architecture built up by oxalate ligands interconnecting Eu 2 O 2 clusters, which are further linked by hydrogen bonding to form a 3D supramolecular framework. The luminescence emission spectrum of compound 1 is also discussed. Both compounds were further investigated by infrared spectroscopy (IR), thermogravimetric analysis (TGA), elemental analyses (EA), and powder X‐ray diffraction (PXRD)." @default.
- W2107792634 created "2016-06-24" @default.
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- W2107792634 date "2011-08-16" @default.
- W2107792634 modified "2023-09-23" @default.
- W2107792634 title "Two Lanthanide-Organic Frameworks Derived from 1H-Benzimidazole-5-Carboxylic Acid and Oxalate Mixed Ligands: Synthesis, Structure and Luminescence Property" @default.
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- W2107792634 doi "https://doi.org/10.1002/zaac.201100168" @default.
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