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- W2108019726 abstract "Abstract The crystal structure of Ag[SC(NH 2 ) 2 ] 2 SCN was determined from three-dimensional diffractometer data and refined by least-squares to a conventional R factor of 0.044 for 1642 observed reflections. The compound is monoclinic (space group C2 c ) with cell parameters a = 11.072(3), b = 13.838(4), c = 13.983(4) A, β = 111.65(3)°, Z =8, d c = 2.123 g cm −3 , d m = 2.11 g cm −3 . Within one complex Ag(tu) 2 SCN unit, three S atoms of two thiourea molecules (AgS 2.482(2) and 2.462(2) A) and of one SCN group (AgS 2.608(2) A) are bonded to the central Ag with almost trigonal planar AgS 3 coordination. One of the two thiourea S atoms is weakly coordinated to a second Ag center (AgS 3.111(2) A), forming a dimeric complex [Ag (tu) 2 SCN] 2 unit with C i symmetry and with a central planar four-membered AgSAgS ring (Ag⋯Ag 3.097(1) A, bond angles SAgS 113.9(1)° and AgSAg 66.1(1)°). The orientation of the bridging thiourea molecule suggests the contribution of electron pairs in pπ carbon-sulfur MO's besides those in sulfur sp 2 orbitals to the AgS bonding system, all bridge bonds being two-electron two-center bonds." @default.
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- W2108019726 date "1976-01-01" @default.
- W2108019726 modified "2023-10-05" @default.
- W2108019726 title "The crystal and molecular structure of thiocyanatobis(thiourea)silver(I)" @default.
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- W2108019726 doi "https://doi.org/10.1016/s0020-1693(00)95599-3" @default.
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