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- W2108049194 abstract "Abstract Acyclic 1,7‐ and 1,8‐enynes with the alkyne moiety directly connected to the asymmetric carbon of an ethyl acetal have been obtained in two steps from the corresponding aldehydes. Ring‐closing metathesis of these enynes delivered the corresponding six‐ and seven‐membered cyclic 1,3‐dienes in moderate‐to‐excellent yields. A competitive ethylene insertion into the alkyne moiety leading to trienes was observed for some substrates depending on their structure and relative configuration." @default.
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- W2108049194 date "2010-08-03" @default.
- W2108049194 modified "2023-09-25" @default.
- W2108049194 title "Ring‐Closing of 1,7‐ and 1,8‐Enynes of Propargylic <i>O</i>,<i>O</i>‐Acetals by Ruthenium‐Catalysed Intramolecular Metathesis" @default.
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- W2108049194 doi "https://doi.org/10.1002/ejoc.201000305" @default.
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