FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108134150> ?p ?o ?g. }

• W2108134150 endingPage "270" @default.
• W2108134150 startingPage "262" @default.
• W2108134150 abstract "New carbosilane monomers R1R2R3SiXSiH3 (X=CH2CH2 and CH(CH3); R1=H, R2=Me, R3=Ph (1a); R1=H, R2, R3=Ph (2a); R1, R2, R3=Et (3a) bearing primary and/or tertiary SiH groups undergo Cp2TiCl2/n-BuLi catalyzed dehydropolymerization selectively at the primary SiH site to afford the corresponding oligosilanes 1–3, [R1R2R3SiXSiH]n (n=12–15). Treatment of the oligosilanes 1 and 2 with methanol in the presence of a catalytic amount of biguanide base results in the chemoselective transformation of the pendant carbosilyl SiH to SiOMe groups, yielding the methoxy- substituted oligosilanes 4 and 5 (R1=OMe), respectively. The reaction of 3 with methanol under a similar base catalyzed conditions reveals only 5% conversion of the skeletal SiH to SiOMe groups. The oligosilanes 1–5 are characterized by IR, UV, 1H, 13C, 29Si, (1H–29Si) HSQC-NMR spectroscopy, GPC and TGA." @default.
• W2108134150 created "2016-06-24" @default.
• W2108134150 creator A5015378885 @default.
• W2108134150 creator A5082571486 @default.
• W2108134150 creator A5090308613 @default.
• W2108134150 date "2001-05-01" @default.
• W2108134150 modified "2023-09-27" @default.
• W2108134150 title "Synthesis and reactivity of novel oligosilanes bearing functional carbosilane side chains" @default.
• W2108134150 cites W1973704750 @default.
• W2108134150 cites W1979461927 @default.
• W2108134150 cites W1982336369 @default.
• W2108134150 cites W1983593212 @default.
• W2108134150 cites W1985201636 @default.
• W2108134150 cites W1988168939 @default.
• W2108134150 cites W1988539245 @default.
• W2108134150 cites W1990296802 @default.
• W2108134150 cites W1991289402 @default.
• W2108134150 cites W1992617759 @default.
• W2108134150 cites W1994097548 @default.
• W2108134150 cites W1998492004 @default.
• W2108134150 cites W2000807575 @default.
• W2108134150 cites W2004246525 @default.
• W2108134150 cites W2009246196 @default.
• W2108134150 cites W2009318072 @default.
• W2108134150 cites W2009693831 @default.
• W2108134150 cites W2009853420 @default.
• W2108134150 cites W2012558648 @default.
• W2108134150 cites W2013731683 @default.
• W2108134150 cites W2013809977 @default.
• W2108134150 cites W2018095142 @default.
• W2108134150 cites W2021852794 @default.
• W2108134150 cites W2022719492 @default.
• W2108134150 cites W2024198821 @default.
• W2108134150 cites W2029432116 @default.
• W2108134150 cites W2033393887 @default.
• W2108134150 cites W2045509999 @default.
• W2108134150 cites W2047960425 @default.
• W2108134150 cites W2048916199 @default.
• W2108134150 cites W2057745343 @default.
• W2108134150 cites W2058722243 @default.
• W2108134150 cites W2059023046 @default.
• W2108134150 cites W2060391823 @default.
• W2108134150 cites W2061456942 @default.
• W2108134150 cites W2061723420 @default.
• W2108134150 cites W2070927199 @default.
• W2108134150 cites W2074777089 @default.
• W2108134150 cites W2075011208 @default.
• W2108134150 cites W2075335160 @default.
• W2108134150 cites W2082452110 @default.
• W2108134150 cites W2083944003 @default.
• W2108134150 cites W2086907838 @default.
• W2108134150 cites W2087234512 @default.
• W2108134150 cites W2088740226 @default.
• W2108134150 cites W2094416201 @default.
• W2108134150 cites W2094601916 @default.
• W2108134150 cites W2099169368 @default.
• W2108134150 cites W2132009441 @default.
• W2108134150 cites W2139723991 @default.
• W2108134150 cites W2200313779 @default.
• W2108134150 cites W2312919004 @default.
• W2108134150 cites W2313739721 @default.
• W2108134150 cites W2949359907 @default.
• W2108134150 cites W2950579169 @default.
• W2108134150 cites W2951368869 @default.
• W2108134150 cites W4211250996 @default.
• W2108134150 cites W4247108391 @default.
• W2108134150 cites W4255370516 @default.
• W2108134150 doi "https://doi.org/10.1016/s0022-328x(01)00784-7" @default.
• W2108134150 hasPublicationYear "2001" @default.
• W2108134150 type Work @default.
• W2108134150 sameAs 2108134150 @default.
• W2108134150 citedByCount "18" @default.
• W2108134150 countsByYear W21081341502012 @default.
• W2108134150 countsByYear W21081341502013 @default.
• W2108134150 countsByYear W21081341502015 @default.
• W2108134150 countsByYear W21081341502016 @default.
• W2108134150 countsByYear W21081341502017 @default.
• W2108134150 countsByYear W21081341502019 @default.
• W2108134150 crossrefType "journal-article" @default.
• W2108134150 hasAuthorship W2108134150A5015378885 @default.
• W2108134150 hasAuthorship W2108134150A5082571486 @default.
• W2108134150 hasAuthorship W2108134150A5090308613 @default.
• W2108134150 hasConcept C142724271 @default.
• W2108134150 hasConcept C155647269 @default.
• W2108134150 hasConcept C161790260 @default.
• W2108134150 hasConcept C166940927 @default.
• W2108134150 hasConcept C178790620 @default.
• W2108134150 hasConcept C185592680 @default.
• W2108134150 hasConcept C204787440 @default.
• W2108134150 hasConcept C204921945 @default.
• W2108134150 hasConcept C2776910235 @default.
• W2108134150 hasConcept C2779607525 @default.
• W2108134150 hasConcept C521977710 @default.
• W2108134150 hasConcept C71240020 @default.
• W2108134150 hasConcept C71924100 @default.
• W2108134150 hasConceptScore W2108134150C142724271 @default.
• W2108134150 hasConceptScore W2108134150C155647269 @default.
• W2108134150 hasConceptScore W2108134150C161790260 @default.

• next