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- W2108178873 endingPage "1839" @default.
- W2108178873 startingPage "1829" @default.
- W2108178873 abstract "A study of the oxidation of poly(vinyl alcohol) (PVAL) by potassium persulfate (KPS) in aqueous solutions showed that the decomposition of KPS was greatly enhanced by the presence of PVAL, its hydroxyl groups being oxidized to ketones in a yield of about one mole of ketone from one mole of KPS. The decomposition rate of KPS was found to be given by the equation, −d[S2O82−]/dt = k[S2O82−] [PVAL]1/2, which was essentially the same as in the oxidation of alcohols of low molecular weight by persulfate ion. The occurrence of gelation of PVAL solutions and graft copolymerization of methyl methacrylate (MMA) onto PVAL in the presence of KPS was evidence for PVAL radical as an intermediate species in the oxidation of PVAL. A characterization study was also carried out for the reaction products of the graft copolymerization of MMA onto PVAL with KPS in dimethyl sulfoxide solution." @default.
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- W2108178873 date "1974-08-01" @default.
- W2108178873 modified "2023-10-11" @default.
- W2108178873 title "Reaction of poly(vinyl alcohol) with potassium persulfate and graft copolymerization" @default.
- W2108178873 doi "https://doi.org/10.1002/pol.1974.170120823" @default.
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