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- W2108181749 abstract "The two ligands 3,3′-dicyanobiphenyl (3) and 5,5′-dicyano-2,2′-bithiophene (4) are geometrically similar but give rise to different coordination compounds when reacted with silver(I) salts. The crystal structures of 3·AgClO4 and 3·AgBF4 have 1 : 1 ligand : cation ratios, while 42·ClO4 and 42·BF4 have 2 : 1 ligand : cation ratios. These ratios for the solid-state materials were constant, even when different stoichiometric ratios were used in the reaction vessels. The structures of these four coordination compounds are presented and the reasons for the difference in the coordination environments discussed with reference to IR spectroscopic and DFT computational results." @default.
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- W2108181749 date "2009-01-01" @default.
- W2108181749 modified "2023-10-18" @default.
- W2108181749 title "5,5′-Dicyano-2,2′-bithiophene and 3,3′-dicyanobiphenyl: off-axis rod-like ligands for silver(I)" @default.
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- W2108181749 doi "https://doi.org/10.1039/b810479d" @default.
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