Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108185746> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2108185746 abstract "6′-Methoxy-(8S,9R)-cinchonan-9-yl N-tert-butoxycarbonyl-2-pyrrolidinecarboxylate [916748-40-8] C30H39N3O5 (MW 521.65) InChI = 1S/C30H39N3O5/c1-6-19-18-32-15-12-20(19)16-26(32)27(22-11-13-31-24-10-9-21(36-5)17-23(22)24)37-28(34)25-8-7-14-33(25)29(35)38-30(2,3)4/h6,9-11,13,17,19-20,25-27H,1,7-8,12,14-16,18H2,2-5H3/t19-,20-,25-,26-,27+/m0/s1 InChIKey = KXDUYNVLODLRCV-QJORRVHFSA-N (asymmetric organocatalyst, used for asymmetric α-bromination of acyl chlorides)1, 2 Alternate Names: (R)-ProQ; N-Boc-L-Proline Quinine. Physical Data: mp = 116 °C; [α]D25 = + 17 (c = 0.01, CHCl3).3 Form Supplied in: white crystalline solid. Analysis of Reagent Purity: IR, NMR, Elemental analysis.3 Preparative Method: prepared according to the procedure of Lectka and coworkers.3 Purification: purified through a short plug of silica with 99.5% EtOAc/0.5% triethylamine to yield a white solid (foam) and recrystallized from boiling Et2O/hexanes. 6′-Methoxy-(8S, 9S)-cinchonan-9-yl N-tert-butoxycarbonyl-(2S)-2-pyrrolidinecarboxylate [916748-39-5] C30H39N3O5 (MW 521.65) InChI = 1S/C30H39N3O5/c1-6-19-18-32-15-12-20(19)16-26(32)27(22-11-13-31-24-10-9-21(36-5)17-23(22)24)37-28(34)25-8-7-14-33(25)29(35)38-30(2,3)4/h6,9-11,13,17,19-20,25-27H,1,7-8,12,14-16,18H2,2-5H3/t19-,20-,25+,26-,27+/m0/s1 InChIKey = KXDUYNVLODLRCV-RJGJBJKLSA-N (asymmetric organocatalyst, used for asymmetric α-bromination of acyl chlorides)1, 2 Alternate Names: (S)-ProQ; N-Boc-D-Proline Quinine. Physical Data: mp = 134 °C; [α]D25= −78 (c = 0.01,CHCl3).3 Form Supplied in: white crystalline solid; synthesized. Analysis of Reagent Purity: IR, NMR, Elemental analysis.3 Preparative Methods: prepared according to the procedure of Lectka and coworkers.3 Purification: purified through a short plug of silica with 99.5% EtOAc/0.5% triethylamine to yield a white solid (foam) and recrystallized from boiling Et2O/hexanes." @default.
- W2108185746 created "2016-06-24" @default.
- W2108185746 creator A5038570512 @default.
- W2108185746 creator A5089479122 @default.
- W2108185746 date "2013-04-22" @default.
- W2108185746 modified "2023-09-24" @default.
- W2108185746 title "6′-Methoxy-(8S,9R)-cinchonan-9-ylN-tert-butoxycarbonyl-2-pyrrolidinecarboxylate" @default.
- W2108185746 cites W1973588663 @default.
- W2108185746 cites W1976431028 @default.
- W2108185746 cites W2018584158 @default.
- W2108185746 cites W2019445932 @default.
- W2108185746 cites W2019656416 @default.
- W2108185746 cites W2020199022 @default.
- W2108185746 cites W2022315139 @default.
- W2108185746 cites W2030204001 @default.
- W2108185746 cites W2035498129 @default.
- W2108185746 cites W2085335257 @default.
- W2108185746 cites W2096937981 @default.
- W2108185746 cites W2108880523 @default.
- W2108185746 cites W2141572176 @default.
- W2108185746 cites W2142269564 @default.
- W2108185746 cites W2949323401 @default.
- W2108185746 cites W2949834663 @default.
- W2108185746 doi "https://doi.org/10.1002/047084289x.rn01564" @default.
- W2108185746 hasPublicationYear "2013" @default.
- W2108185746 type Work @default.
- W2108185746 sameAs 2108185746 @default.
- W2108185746 citedByCount "0" @default.
- W2108185746 crossrefType "reference-entry" @default.
- W2108185746 hasAuthorship W2108185746A5038570512 @default.
- W2108185746 hasAuthorship W2108185746A5089479122 @default.
- W2108185746 hasConcept C134121241 @default.
- W2108185746 hasConcept C13965031 @default.
- W2108185746 hasConcept C155647269 @default.
- W2108185746 hasConcept C178790620 @default.
- W2108185746 hasConcept C185592680 @default.
- W2108185746 hasConcept C191897082 @default.
- W2108185746 hasConcept C192562407 @default.
- W2108185746 hasConcept C2781283055 @default.
- W2108185746 hasConcept C40875361 @default.
- W2108185746 hasConcept C65973085 @default.
- W2108185746 hasConcept C71240020 @default.
- W2108185746 hasConceptScore W2108185746C134121241 @default.
- W2108185746 hasConceptScore W2108185746C13965031 @default.
- W2108185746 hasConceptScore W2108185746C155647269 @default.
- W2108185746 hasConceptScore W2108185746C178790620 @default.
- W2108185746 hasConceptScore W2108185746C185592680 @default.
- W2108185746 hasConceptScore W2108185746C191897082 @default.
- W2108185746 hasConceptScore W2108185746C192562407 @default.
- W2108185746 hasConceptScore W2108185746C2781283055 @default.
- W2108185746 hasConceptScore W2108185746C40875361 @default.
- W2108185746 hasConceptScore W2108185746C65973085 @default.
- W2108185746 hasConceptScore W2108185746C71240020 @default.
- W2108185746 hasLocation W21081857461 @default.
- W2108185746 hasOpenAccess W2108185746 @default.
- W2108185746 hasPrimaryLocation W21081857461 @default.
- W2108185746 hasRelatedWork W2012320598 @default.
- W2108185746 hasRelatedWork W2097014657 @default.
- W2108185746 hasRelatedWork W2352522567 @default.
- W2108185746 hasRelatedWork W2360529013 @default.
- W2108185746 hasRelatedWork W2385352450 @default.
- W2108185746 hasRelatedWork W2401773896 @default.
- W2108185746 hasRelatedWork W2949184651 @default.
- W2108185746 hasRelatedWork W2951242184 @default.
- W2108185746 hasRelatedWork W2952076161 @default.
- W2108185746 hasRelatedWork W3150053629 @default.
- W2108185746 isParatext "false" @default.
- W2108185746 isRetracted "false" @default.
- W2108185746 magId "2108185746" @default.
- W2108185746 workType "reference-entry" @default.