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- W2108241830 abstract "Abstract Hydrothermal reactions of cadmium(II) or zinc(II) ion with dimethyl methylsulfonomethanephosphonate afforded two new layered metal phosphonates with µ 2-H2O or µ 3-OH− as co-ligand, [Cd2(L)2(H2O)] (1) and [Zn3(L)2(OH)2] (2) (L2− = ). The layered structure in 1 features two types of topologically similar tubes arranged in a crisscross pattern, one of which accommodates µ 2-H2O ligands located at the tube center. The µ 3-OH− ligands in 2 bridge the Zn2+ to build a layered framework which features edge-sharing Zn6O6 rings; furthermore, a pair of pentadentate L2− ligands, each binding four Zn2+ ions, cap the Zn6O6 ring above and below to form a Zn6P2O12 cage related by 2-fold symmetry. Keywords: CadmiumZincPhosphonateOxo-bridgingLayered structure Acknowledgments The work was supported by the National Natural Science Foundation of China (No. 21061001) and the Natural Science Foundation of Jiangxi Provincial Education Department (No. GJJ10714)." @default.
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- W2108241830 date "2012-02-21" @default.
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- W2108241830 title "Tube- or cage-containing layered cadmium(II) and zinc(II) phosphonates decorated by sulfone groups" @default.
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- W2108241830 doi "https://doi.org/10.1080/00958972.2012.662642" @default.
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