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• W2108325890 abstract "Herein, we report the manganese complex with a novel trianionic ligand, the pentafluorophenyldipyrrinphenol ligand DPPH3. The X-ray crystal structure reveals that the MnIII complex exists in a dimeric form in the solid state. Electrochemical studies indicate two quasi-reversible one electron oxidation processes. EPR data on the one electron oxidised species in solution support the formation of a monuclear Mn complex with an S = 3/2 spin system. Preliminary studies towards epoxidation reactions were tested in the presence of iodosylbenzene (PhIO) and are in favour of an oxygen-atom-transfer (OAT) reaction catalyzed by the MnIII complex." @default.
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• W2108325890 date "2011-01-01" @default.
• W2108325890 modified "2023-10-17" @default.
• W2108325890 title "Dipyrrinphenol–Mn(iii) complex: synthesis, electrochemistry, spectroscopic characterisation and reactivity" @default.
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• W2108325890 doi "https://doi.org/10.1039/c1dt10868a" @default.
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