Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108350789> ?p ?o ?g. }
- W2108350789 endingPage "1510" @default.
- W2108350789 startingPage "1498" @default.
- W2108350789 abstract "Abstract Atom transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP) were combined to synthesize poly(ϵ‐caprolactone‐ co ‐octadecyl methacrylate‐ co ‐dimethylaminoethyl methacrylate) copolymers possessing a triblock or random block structure. Various synthetic pathways (sequential or simultaneous approaches) were investigated for the synthesis of both copolymers. For the preparation of these copolymers, an initiator with dual functionality for ATRP/anionic ring‐opening polymerization, 2‐hydroxyethyl 2‐bromoisobutyrate, was used. Copolymers were prepared with good structural control and low polydispersities (weight‐average molecular weight/number‐average molecular weight < 1.2), but one limitation was identified: the dimethylaminoethyl methacrylate (DMAEMA) block had to be synthesized after the ϵ‐caprolactone block. ROP could not proceed in the presence of DMAEMA because the complexation of the amine groups in poly(dimethylaminoethyl methacrylate) deactivated tin(II) hexanoate, which was used as a catalyst for ROP. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1498–1510, 2005" @default.
- W2108350789 created "2016-06-24" @default.
- W2108350789 creator A5006612391 @default.
- W2108350789 creator A5056539244 @default.
- W2108350789 creator A5058597183 @default.
- W2108350789 creator A5076056437 @default.
- W2108350789 date "2005-02-15" @default.
- W2108350789 modified "2023-10-16" @default.
- W2108350789 title "Block and random copolymers as surfactants for dispersion polymerization. I. Synthesis via atom transfer radical polymerization and ring-opening polymerization" @default.
- W2108350789 cites W141053126 @default.
- W2108350789 cites W1966863664 @default.
- W2108350789 cites W1969299640 @default.
- W2108350789 cites W1970723452 @default.
- W2108350789 cites W1971216193 @default.
- W2108350789 cites W1979062047 @default.
- W2108350789 cites W1985377575 @default.
- W2108350789 cites W1992258152 @default.
- W2108350789 cites W1999034326 @default.
- W2108350789 cites W1999126616 @default.
- W2108350789 cites W2001220467 @default.
- W2108350789 cites W2002064117 @default.
- W2108350789 cites W2005974429 @default.
- W2108350789 cites W2007254289 @default.
- W2108350789 cites W2008443986 @default.
- W2108350789 cites W2013749421 @default.
- W2108350789 cites W2014172913 @default.
- W2108350789 cites W2020213182 @default.
- W2108350789 cites W2021685410 @default.
- W2108350789 cites W2032267541 @default.
- W2108350789 cites W2032712421 @default.
- W2108350789 cites W2037550000 @default.
- W2108350789 cites W2039085236 @default.
- W2108350789 cites W2039143442 @default.
- W2108350789 cites W2044594163 @default.
- W2108350789 cites W2044622839 @default.
- W2108350789 cites W2045361084 @default.
- W2108350789 cites W2045682019 @default.
- W2108350789 cites W2046143166 @default.
- W2108350789 cites W2055393399 @default.
- W2108350789 cites W2056201335 @default.
- W2108350789 cites W2056525580 @default.
- W2108350789 cites W2057667428 @default.
- W2108350789 cites W2060571716 @default.
- W2108350789 cites W2063917429 @default.
- W2108350789 cites W2071082385 @default.
- W2108350789 cites W2075920074 @default.
- W2108350789 cites W2077904702 @default.
- W2108350789 cites W2085735879 @default.
- W2108350789 cites W2088355061 @default.
- W2108350789 cites W2118705131 @default.
- W2108350789 cites W2127576005 @default.
- W2108350789 cites W2144122182 @default.
- W2108350789 cites W341902245 @default.
- W2108350789 cites W37958052 @default.
- W2108350789 cites W4229968316 @default.
- W2108350789 cites W4230210408 @default.
- W2108350789 cites W53832620 @default.
- W2108350789 cites W600996593 @default.
- W2108350789 cites W617009719 @default.
- W2108350789 cites W630939963 @default.
- W2108350789 doi "https://doi.org/10.1002/pola.20629" @default.
- W2108350789 hasPublicationYear "2005" @default.
- W2108350789 type Work @default.
- W2108350789 sameAs 2108350789 @default.
- W2108350789 citedByCount "110" @default.
- W2108350789 countsByYear W21083507892012 @default.
- W2108350789 countsByYear W21083507892013 @default.
- W2108350789 countsByYear W21083507892014 @default.
- W2108350789 countsByYear W21083507892015 @default.
- W2108350789 countsByYear W21083507892016 @default.
- W2108350789 countsByYear W21083507892017 @default.
- W2108350789 countsByYear W21083507892018 @default.
- W2108350789 countsByYear W21083507892019 @default.
- W2108350789 countsByYear W21083507892020 @default.
- W2108350789 countsByYear W21083507892021 @default.
- W2108350789 countsByYear W21083507892022 @default.
- W2108350789 crossrefType "journal-article" @default.
- W2108350789 hasAuthorship W2108350789A5006612391 @default.
- W2108350789 hasAuthorship W2108350789A5056539244 @default.
- W2108350789 hasAuthorship W2108350789A5058597183 @default.
- W2108350789 hasAuthorship W2108350789A5076056437 @default.
- W2108350789 hasConcept C111998727 @default.
- W2108350789 hasConcept C121120078 @default.
- W2108350789 hasConcept C132050475 @default.
- W2108350789 hasConcept C150539798 @default.
- W2108350789 hasConcept C15920480 @default.
- W2108350789 hasConcept C178790620 @default.
- W2108350789 hasConcept C185592680 @default.
- W2108350789 hasConcept C188027245 @default.
- W2108350789 hasConcept C192562407 @default.
- W2108350789 hasConcept C203897987 @default.
- W2108350789 hasConcept C2777492985 @default.
- W2108350789 hasConcept C44228677 @default.
- W2108350789 hasConcept C48396125 @default.
- W2108350789 hasConcept C521977710 @default.
- W2108350789 hasConcept C89760097 @default.
- W2108350789 hasConceptScore W2108350789C111998727 @default.
- W2108350789 hasConceptScore W2108350789C121120078 @default.