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- W2108396145 abstract "A novel hexa-armed and star-shaped polymer containing cholesterol end-capped poly(ε-caprolactone) arms emanating from a phosphazene core (N3P3-(PCL-Chol)6) was synthesized by a combination of ring-opening polymerization and “click” chemistry techniques. For this purpose, the terminal OH groups of the synthesized precursor (N3P3-(PCL-OH)6) were converted into –Chol through a series of reaction. Both N3P3-(PCL-OH)6 and N3P3-(PCL-Chol)6 were then employed in the preparation of supramolecular inclusion complexes (ICs) with β-cyclodextrin (β-CD). The latter formed ICs with β-CD in higher yield. The host–guest stoichiometry (ε-CL:β-CD, mol:mol) in the ICs of N3P3-(PCL-Chol)6 was found to be 1.2. The formation of supramolecular ICs of N3P3-(PCL-Chol)6 with β-CD was confirmed by using Fourier transform infrared (FTIR) and 1H nuclear magnetic resonance (NMR) spectroscopic methods, wide-angle X-ray diffraction (WAXD), and thermal analysis techniques. WAXD data showed that the obtained ICs with N3P3-(PCL-Chol)6 had a channel-type crystalline structure, indicating the suppression of the original crystallization of N3P3-(PCL-Chol)6 in β-CD cavities. Moreover, the thermal stabilities of ICs were found to be higher than those of the free star polymer and β-CD. Furthermore, the surface properties of N3P3-(PCL-Chol)6 and its ICs with β-CD were investigated by static contact angle measurements. The obtained results proved that the wettability of N3P3-(PCL-Chol)6 successfully increased with the formation of its ICs with β-CD. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 3406–3420" @default.
- W2108396145 created "2016-06-24" @default.
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- W2108396145 date "2014-09-25" @default.
- W2108396145 modified "2023-10-03" @default.
- W2108396145 title "Supramolecular inclusion complexes of a star polymer containing cholesterol end-capped poly(ε-caprolactone) arms with β-cyclodextrin" @default.
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- W2108396145 doi "https://doi.org/10.1002/pola.27408" @default.
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