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- W2108447247 abstract "Bei der Thermolyse von 1, 2-Di-tert-butyldiphosphan, H(t-Bu) PP(t-Bu) H, entsteht aus dem zunächst gebildeten iso-P5H5-Derivat P5(t-Bu)4H [3] durch Weiterreaktion mit H2(t-BuP)2 oder H2(t-BuP)3 das bislang unbekannte Hexaphosphan P6(t-Bu)5H (1). Verbindung 1 wurde in reiner Form isoliert und strukturell als 1-(1, 2-Di-tert-butyldiphosphino)-2, 3, 4-tri-tert-butyl-cyclotetraphosphan, d. h. als Vierring-Verbindung mit P2-Seitenkette, charakterisiert. Wegen der Chiralität der P-Atome in der Seitenkette liegt 1 als Gemisch aus zwei Konfigurationsisomeren, der threo- und erythro-Form, vor. Contributions to the Chemistry of Phosphorus. 142. P6(t-Bu)5H – the First Cyclotetraphosphane with a P2 Side Chain The thermolysis of 1, 2-di-tert-butyldiphosphane, H(t-Bu)PP(t-Bu)H, leads to formation of the hitherto unknown hexaphosphane P6(t-Bu)5H (1). In the first instance the iso-P5H5 derivative P5(t-Bu)4H [3] is formed, which reacts further with H2(t-BuP)2 or H2(t-BuP)3 yielding 1. Compound 1 has been isolated in the pure state and structurally characterized as 1-(1,2-di-tert-butyldiphosphino)-2, 3, 4-tri-tert-butyl-cyclotetraphosphane, i. e. as a four-membered ring compound with a P2 side chain. Due to the chirality of the P atoms in the side chain, 1 exists as a mixture of two configurational isomers, the threo-and the erythro-form." @default.
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- W2108447247 date "1984-09-01" @default.
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- W2108447247 title "Beitr�ge zur Chemie des Phosphors. 142. P6(t-Bu)5H - das erste Cyclotetraphosphan mit P2-Seitenkette" @default.
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- W2108447247 doi "https://doi.org/10.1002/zaac.19845160902" @default.
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