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- W2108482110 abstract "The redox properties of 23 alternant PAH and non-alternant mono- and bis-CP-PAH that contain annelated peripheral pentagons were determined using cyclic voltammetry. The results show that peripheral cyclopenta-fusion markedly enhances their electron affinity. Unexpectedly for the non-alternant PAH, a good linear correlation between the first reduction potential [E1/2(0/−1) V vs. SCE] and their standard Hückel LUMO energy (−εLUMO/β) is found. This indicates that the peripheral pentagons perturb the LUMO of the original alternant PAH core in a systematic fashion. A survey of the reduction behaviour of the mono- and bis-CP-PAH reveals that upon reduction the effect of the cyclopenta-moiety on the remainder of the molecule becomes negligible. Evidence for the formation of 6π-electron cyclopentadienide sub-structures is obtained, i.e. localization of the added electrons in the peripheral pentagons occurs." @default.
- W2108482110 created "2016-06-24" @default.
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- W2108482110 creator A5034387274 @default.
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- W2108482110 date "2004-01-01" @default.
- W2108482110 modified "2023-10-11" @default.
- W2108482110 title "Redox properties of non-alternant cyclopenta-fused polycyclic aromatic hydrocarbons: The effect of peripheral pentagon annelation" @default.
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- W2108482110 doi "https://doi.org/10.1039/b312234d" @default.
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