Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108492893> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2108492893 endingPage "461" @default.
- W2108492893 startingPage "457" @default.
- W2108492893 abstract "The kinetics of the formation of the titanium-peroxide [TiO2+2] complex from the reaction of Ti(IV)OSO4 with hydrogen peroxide and the hydrolysis of hydroxymethyl hydroperoxide (HMHP) were examined to determine whether Ti(IV)OSO4 could be used to distinguish between hydrogen peroxide and HMHP in mixed solutions. Stopped-flow analysis coupled to UV-vis spectroscopy was used to examine the reaction kinetics at various temperatures. The molar absorptivity (ε) of the [TiO2+2] complex was found to be 679.5 ± 20.8 L mol−1 cm−1 at 405 nm. The reaction between hydrogen peroxide and Ti(IV)OSO4 was first order with respect to both Ti(IV)OSO4 and H2O2 with a rate constant of 5.70 ± 0.18 × 104 M−1 s−1 at 25°C, and an activation energy, Ea = 40.5 ± 1.9 kJ mol−1. The rate constant for the hydrolysis of HMHP was 4.3 × 10−3 s−1 at pH 8.5. Since the rate of complex formation between Ti(IV)OSO4 and hydrogen peroxide is much faster than the rate of hydrolysis of HMHP, the Ti(IV)OSO4 reaction coupled to time-dependent UV-vis spectroscopic measurements can be used to distinguish between hydrogen peroxide and HMHP in solution. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 457–461, 2007" @default.
- W2108492893 created "2016-06-24" @default.
- W2108492893 creator A5032383582 @default.
- W2108492893 creator A5078202069 @default.
- W2108492893 date "2007-01-01" @default.
- W2108492893 modified "2023-09-24" @default.
- W2108492893 title "The kinetics of complex formation between Ti(IV) and hydrogen peroxide" @default.
- W2108492893 cites W1992027337 @default.
- W2108492893 cites W1994145659 @default.
- W2108492893 cites W2015152640 @default.
- W2108492893 cites W2016363836 @default.
- W2108492893 cites W2027244517 @default.
- W2108492893 cites W2027899818 @default.
- W2108492893 cites W2034643367 @default.
- W2108492893 cites W2035122585 @default.
- W2108492893 cites W2037949244 @default.
- W2108492893 cites W2052344505 @default.
- W2108492893 cites W2061555491 @default.
- W2108492893 cites W2061570786 @default.
- W2108492893 cites W2061621310 @default.
- W2108492893 cites W2070881948 @default.
- W2108492893 cites W2074020459 @default.
- W2108492893 cites W2076950227 @default.
- W2108492893 cites W2088336457 @default.
- W2108492893 cites W4237395943 @default.
- W2108492893 doi "https://doi.org/10.1002/kin.20259" @default.
- W2108492893 hasPublicationYear "2007" @default.
- W2108492893 type Work @default.
- W2108492893 sameAs 2108492893 @default.
- W2108492893 citedByCount "54" @default.
- W2108492893 countsByYear W21084928932013 @default.
- W2108492893 countsByYear W21084928932014 @default.
- W2108492893 countsByYear W21084928932015 @default.
- W2108492893 countsByYear W21084928932016 @default.
- W2108492893 countsByYear W21084928932017 @default.
- W2108492893 countsByYear W21084928932018 @default.
- W2108492893 countsByYear W21084928932019 @default.
- W2108492893 countsByYear W21084928932020 @default.
- W2108492893 countsByYear W21084928932021 @default.
- W2108492893 countsByYear W21084928932022 @default.
- W2108492893 countsByYear W21084928932023 @default.
- W2108492893 crossrefType "journal-article" @default.
- W2108492893 hasAuthorship W2108492893A5032383582 @default.
- W2108492893 hasAuthorship W2108492893A5078202069 @default.
- W2108492893 hasConcept C120665830 @default.
- W2108492893 hasConcept C121332964 @default.
- W2108492893 hasConcept C13965031 @default.
- W2108492893 hasConcept C147789679 @default.
- W2108492893 hasConcept C148898269 @default.
- W2108492893 hasConcept C178790620 @default.
- W2108492893 hasConcept C179104552 @default.
- W2108492893 hasConcept C185592680 @default.
- W2108492893 hasConcept C2781048764 @default.
- W2108492893 hasConcept C533411734 @default.
- W2108492893 hasConcept C62520636 @default.
- W2108492893 hasConcept C75473681 @default.
- W2108492893 hasConcept C76046532 @default.
- W2108492893 hasConcept C93391505 @default.
- W2108492893 hasConcept C94412978 @default.
- W2108492893 hasConcept C95121573 @default.
- W2108492893 hasConceptScore W2108492893C120665830 @default.
- W2108492893 hasConceptScore W2108492893C121332964 @default.
- W2108492893 hasConceptScore W2108492893C13965031 @default.
- W2108492893 hasConceptScore W2108492893C147789679 @default.
- W2108492893 hasConceptScore W2108492893C148898269 @default.
- W2108492893 hasConceptScore W2108492893C178790620 @default.
- W2108492893 hasConceptScore W2108492893C179104552 @default.
- W2108492893 hasConceptScore W2108492893C185592680 @default.
- W2108492893 hasConceptScore W2108492893C2781048764 @default.
- W2108492893 hasConceptScore W2108492893C533411734 @default.
- W2108492893 hasConceptScore W2108492893C62520636 @default.
- W2108492893 hasConceptScore W2108492893C75473681 @default.
- W2108492893 hasConceptScore W2108492893C76046532 @default.
- W2108492893 hasConceptScore W2108492893C93391505 @default.
- W2108492893 hasConceptScore W2108492893C94412978 @default.
- W2108492893 hasConceptScore W2108492893C95121573 @default.
- W2108492893 hasIssue "8" @default.
- W2108492893 hasLocation W21084928931 @default.
- W2108492893 hasOpenAccess W2108492893 @default.
- W2108492893 hasPrimaryLocation W21084928931 @default.
- W2108492893 hasRelatedWork W1966696631 @default.
- W2108492893 hasRelatedWork W2028982140 @default.
- W2108492893 hasRelatedWork W2052832096 @default.
- W2108492893 hasRelatedWork W2091921029 @default.
- W2108492893 hasRelatedWork W2108492893 @default.
- W2108492893 hasRelatedWork W2144875972 @default.
- W2108492893 hasRelatedWork W2329461958 @default.
- W2108492893 hasRelatedWork W2377233444 @default.
- W2108492893 hasRelatedWork W2952785262 @default.
- W2108492893 hasRelatedWork W2503403438 @default.
- W2108492893 hasVolume "39" @default.
- W2108492893 isParatext "false" @default.
- W2108492893 isRetracted "false" @default.
- W2108492893 magId "2108492893" @default.
- W2108492893 workType "article" @default.