Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108506150> ?p ?o ?g. }
- W2108506150 endingPage "2914" @default.
- W2108506150 startingPage "2908" @default.
- W2108506150 abstract "The luminescent organosilicon copolymers poly(silafluorenyldiethynylspirobifluorene) and poly(tetrasilolediethynylspirobifluorene) have been covalently linked to a silica gel thin layer chromatography (TLC) support through the use of a trimethoxysilyl end group. Surface functionalization of silica with the fluorescent sensing polymer allows for more efficient quenching by the analyte, due to the small amount of fluorophore present, thus yielding enhanced detection sensitivity. The attachment of the sensing polymers onto a chromatographic support also allows for simultaneous separation of an explosive mixture, and component identification through the use of multiple sensing polymers. In a 1.0 mm2 area solution spotted onto the fluorescent silica plate, detection limits obtained for the explosives TNT (2,4,6-trinitrotoluene), DNT (2,6-dinitrotoluene), PA (picric acid), Tetryl (N-methyl-N,2,4,6-tetranitroaniline), HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), RDX (1,3,5-trinitro-1,3,5-triazacyclohexane), and Cl-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) ranged from 4 to 750 pg mm−2. Since less than 350 pg of highly fluorescent polymer is required to coat each TLC plate, the relatively small amounts of explosive being detected still represent an excess of quencher over sensing fluorophore." @default.
- W2108506150 created "2016-06-24" @default.
- W2108506150 creator A5031828271 @default.
- W2108506150 creator A5036422127 @default.
- W2108506150 creator A5066313721 @default.
- W2108506150 creator A5081791191 @default.
- W2108506150 date "2012-01-01" @default.
- W2108506150 modified "2023-09-25" @default.
- W2108506150 title "Silica anchored fluorescent organosilicon polymers for explosives separation and detection" @default.
- W2108506150 cites W1971393110 @default.
- W2108506150 cites W1976725488 @default.
- W2108506150 cites W1977308064 @default.
- W2108506150 cites W1978341800 @default.
- W2108506150 cites W1978805494 @default.
- W2108506150 cites W1979801291 @default.
- W2108506150 cites W1981754932 @default.
- W2108506150 cites W1984990803 @default.
- W2108506150 cites W1997462263 @default.
- W2108506150 cites W1997849519 @default.
- W2108506150 cites W1999006280 @default.
- W2108506150 cites W2002905730 @default.
- W2108506150 cites W2003189761 @default.
- W2108506150 cites W2004891652 @default.
- W2108506150 cites W2005025295 @default.
- W2108506150 cites W2005886767 @default.
- W2108506150 cites W2007908253 @default.
- W2108506150 cites W2009057700 @default.
- W2108506150 cites W2016073992 @default.
- W2108506150 cites W2017232207 @default.
- W2108506150 cites W2022500341 @default.
- W2108506150 cites W2032185182 @default.
- W2108506150 cites W2032462758 @default.
- W2108506150 cites W2033654208 @default.
- W2108506150 cites W2042246367 @default.
- W2108506150 cites W2044777503 @default.
- W2108506150 cites W2044881444 @default.
- W2108506150 cites W2045421387 @default.
- W2108506150 cites W2046878170 @default.
- W2108506150 cites W2052279591 @default.
- W2108506150 cites W2052541556 @default.
- W2108506150 cites W2054808993 @default.
- W2108506150 cites W2065539909 @default.
- W2108506150 cites W2066733132 @default.
- W2108506150 cites W2066836207 @default.
- W2108506150 cites W2070413963 @default.
- W2108506150 cites W2076751050 @default.
- W2108506150 cites W2077764539 @default.
- W2108506150 cites W2078508078 @default.
- W2108506150 cites W2082366842 @default.
- W2108506150 cites W2082816548 @default.
- W2108506150 cites W2082974977 @default.
- W2108506150 cites W2088399620 @default.
- W2108506150 cites W2095569014 @default.
- W2108506150 cites W2096543658 @default.
- W2108506150 cites W2104573361 @default.
- W2108506150 cites W2119514457 @default.
- W2108506150 cites W2141070669 @default.
- W2108506150 cites W2142886073 @default.
- W2108506150 cites W2145214996 @default.
- W2108506150 cites W2165344788 @default.
- W2108506150 cites W2312740923 @default.
- W2108506150 cites W2320367232 @default.
- W2108506150 cites W34781523 @default.
- W2108506150 cites W4243229951 @default.
- W2108506150 cites W4245914283 @default.
- W2108506150 cites W4246935071 @default.
- W2108506150 doi "https://doi.org/10.1039/c2jm15214b" @default.
- W2108506150 hasPublicationYear "2012" @default.
- W2108506150 type Work @default.
- W2108506150 sameAs 2108506150 @default.
- W2108506150 citedByCount "45" @default.
- W2108506150 countsByYear W21085061502012 @default.
- W2108506150 countsByYear W21085061502013 @default.
- W2108506150 countsByYear W21085061502014 @default.
- W2108506150 countsByYear W21085061502015 @default.
- W2108506150 countsByYear W21085061502016 @default.
- W2108506150 countsByYear W21085061502017 @default.
- W2108506150 countsByYear W21085061502018 @default.
- W2108506150 countsByYear W21085061502019 @default.
- W2108506150 countsByYear W21085061502020 @default.
- W2108506150 countsByYear W21085061502021 @default.
- W2108506150 countsByYear W21085061502022 @default.
- W2108506150 countsByYear W21085061502023 @default.
- W2108506150 crossrefType "journal-article" @default.
- W2108506150 hasAuthorship W2108506150A5031828271 @default.
- W2108506150 hasAuthorship W2108506150A5036422127 @default.
- W2108506150 hasAuthorship W2108506150A5066313721 @default.
- W2108506150 hasAuthorship W2108506150A5081791191 @default.
- W2108506150 hasConcept C10390740 @default.
- W2108506150 hasConcept C119128265 @default.
- W2108506150 hasConcept C121332964 @default.
- W2108506150 hasConcept C178790620 @default.
- W2108506150 hasConcept C185592680 @default.
- W2108506150 hasConcept C188027245 @default.
- W2108506150 hasConcept C192562407 @default.
- W2108506150 hasConcept C2778617687 @default.
- W2108506150 hasConcept C2778736354 @default.
- W2108506150 hasConcept C2779532046 @default.