Matches in SemOpenAlex for { <https://semopenalex.org/work/W2108518612> ?p ?o ?g. }
- W2108518612 endingPage "129" @default.
- W2108518612 startingPage "121" @default.
- W2108518612 abstract "Two covalently bonded cationic β-CD chiral stationary phases (CSPs) prepared by graft polymerization of 6A-(3-vinylimidazolium)-6-deoxyperphenylcarbamate-β-cyclodextrin chloride or 6A-(N,N-allylmethylammonium)-6-deoxyperphenylcarbamoyl-β-cyclodextrin chloride onto silica gel were successfully applied in high-performance liquid chromatography (HPLC). Their enantioseparation capability was examined with 12 racemic pharmaceuticals and 6 carboxylic acids. The results indicated that imidazolium-containing β-CD CSP afforded more favorable enantioseparations than that containing ammonium moiety under normal-phase HPLC. The cationic moiety on β-CD CSPs could form strong hydrogen bonding with analytes in normal-phase liquid chromatography (NPLC) to enhance the analytes’ retention and enantioseparations. In reversed-phase liquid chromatography (RPLC), the analytes exhibited their maximum retention when the pH of mobile phase was close to their pKa value. Inclusion complexation with CD cavity and columbic/ionic interactions with cationic substituent on the CD rim would afford accentuated retention and enantioseparations of the analytes." @default.
- W2108518612 created "2016-06-24" @default.
- W2108518612 creator A5018953334 @default.
- W2108518612 creator A5046802665 @default.
- W2108518612 creator A5061733983 @default.
- W2108518612 creator A5067723372 @default.
- W2108518612 date "2012-03-01" @default.
- W2108518612 modified "2023-10-17" @default.
- W2108518612 title "Cationic cyclodextrins chemically-bonded chiral stationary phases for high-performance liquid chromatography" @default.
- W2108518612 cites W1520161169 @default.
- W2108518612 cites W1964276662 @default.
- W2108518612 cites W1967052599 @default.
- W2108518612 cites W1972342401 @default.
- W2108518612 cites W1972524792 @default.
- W2108518612 cites W1973083933 @default.
- W2108518612 cites W1974475121 @default.
- W2108518612 cites W1979032084 @default.
- W2108518612 cites W1979814209 @default.
- W2108518612 cites W1981287864 @default.
- W2108518612 cites W1982948691 @default.
- W2108518612 cites W1983224633 @default.
- W2108518612 cites W1989873249 @default.
- W2108518612 cites W1992911862 @default.
- W2108518612 cites W1992932513 @default.
- W2108518612 cites W1993054914 @default.
- W2108518612 cites W1993429718 @default.
- W2108518612 cites W2000143475 @default.
- W2108518612 cites W2005487512 @default.
- W2108518612 cites W2006125058 @default.
- W2108518612 cites W2007867132 @default.
- W2108518612 cites W2010423861 @default.
- W2108518612 cites W2024105179 @default.
- W2108518612 cites W2025791044 @default.
- W2108518612 cites W2026726425 @default.
- W2108518612 cites W2027092780 @default.
- W2108518612 cites W2027913277 @default.
- W2108518612 cites W2032555758 @default.
- W2108518612 cites W2034406436 @default.
- W2108518612 cites W2038278918 @default.
- W2108518612 cites W2038343111 @default.
- W2108518612 cites W2039572111 @default.
- W2108518612 cites W2040434017 @default.
- W2108518612 cites W2045604227 @default.
- W2108518612 cites W2047390716 @default.
- W2108518612 cites W2051770865 @default.
- W2108518612 cites W2052162940 @default.
- W2108518612 cites W2056777375 @default.
- W2108518612 cites W2056814358 @default.
- W2108518612 cites W2058751198 @default.
- W2108518612 cites W2059024100 @default.
- W2108518612 cites W2061711045 @default.
- W2108518612 cites W2068681010 @default.
- W2108518612 cites W2068980133 @default.
- W2108518612 cites W2078056508 @default.
- W2108518612 cites W2079481917 @default.
- W2108518612 cites W2081113717 @default.
- W2108518612 cites W2082484586 @default.
- W2108518612 cites W2083745821 @default.
- W2108518612 cites W2087958604 @default.
- W2108518612 cites W2096231580 @default.
- W2108518612 cites W2103261346 @default.
- W2108518612 cites W2126147415 @default.
- W2108518612 cites W2127134392 @default.
- W2108518612 cites W2157474689 @default.
- W2108518612 cites W2171115159 @default.
- W2108518612 cites W4231087082 @default.
- W2108518612 doi "https://doi.org/10.1016/j.aca.2011.12.063" @default.
- W2108518612 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22305907" @default.
- W2108518612 hasPublicationYear "2012" @default.
- W2108518612 type Work @default.
- W2108518612 sameAs 2108518612 @default.
- W2108518612 citedByCount "41" @default.
- W2108518612 countsByYear W21085186122012 @default.
- W2108518612 countsByYear W21085186122013 @default.
- W2108518612 countsByYear W21085186122014 @default.
- W2108518612 countsByYear W21085186122015 @default.
- W2108518612 countsByYear W21085186122016 @default.
- W2108518612 countsByYear W21085186122017 @default.
- W2108518612 countsByYear W21085186122018 @default.
- W2108518612 countsByYear W21085186122020 @default.
- W2108518612 countsByYear W21085186122021 @default.
- W2108518612 countsByYear W21085186122022 @default.
- W2108518612 countsByYear W21085186122023 @default.
- W2108518612 crossrefType "journal-article" @default.
- W2108518612 hasAuthorship W2108518612A5018953334 @default.
- W2108518612 hasAuthorship W2108518612A5046802665 @default.
- W2108518612 hasAuthorship W2108518612A5061733983 @default.
- W2108518612 hasAuthorship W2108518612A5067723372 @default.
- W2108518612 hasConcept C154881586 @default.
- W2108518612 hasConcept C161790260 @default.
- W2108518612 hasConcept C16838498 @default.
- W2108518612 hasConcept C178790620 @default.
- W2108518612 hasConcept C179998833 @default.
- W2108518612 hasConcept C180577832 @default.
- W2108518612 hasConcept C183882617 @default.
- W2108518612 hasConcept C185592680 @default.
- W2108518612 hasConcept C2776568683 @default.
- W2108518612 hasConcept C2778689049 @default.