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- W2108587736 abstract "Abstract Calix[5]arene ( 2 ) and calix[8]arene ( 4 ) reacted with bis(bromomethyl)‐substituted heterocycles such as pyridine and 1,10‐phenanthroline to give [1+1] condensation products 10 and 16–18 (bridged bimacrocycles) and [2+1] dicalixarenes 11 , 13 and 14 , all of which were fully characterized. Although the bridging capability of both bridging units 5 and 6 is surprisingly similar, calix[5]arene ( 2 ) could only be bridged with the pyridine derivatives 5 . With calix[8]arene ( 4 ), the 1,10‐phenanthroline bridging reagent 6 gave a cleaner product spectrum than the pyridine reagent 5 . The 1,10‐phenanthroline‐bridged calix[8]arene 16 was characterized by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2108587736 date "2005-05-25" @default.
- W2108587736 modified "2023-10-14" @default.
- W2108587736 title "Calix[5]‐ and Calix[8]arenes Bridged with Heterocycles" @default.
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- W2108587736 doi "https://doi.org/10.1002/ejoc.200400774" @default.
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