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- W2108593463 abstract "Abstract Palladium and platinum complexes containing a sulfur‐functionalised N‐heterocyclic carbene (S‐NHC) chelate ligand have been synthesised. The absolute conformations of these novel organometallic S‐NHC chelates were determined by X‐ray structural analyses and solution‐phase 2D 1 H– 1 H ROESY NMR spectroscopy. The structural studies revealed that the phenyl substituents on the stereogenic carbon atoms invariably take up the axial positions on the Pd‐C‐S coordination plane to afford a skewed five‐membered ring structure. All of the chiral complexes are structurally rigid and stereochemically locked in a chiral ring conformation that is either ( R s , S , R )‐λ or ( S s , R , R )‐δ in both the solid state and solution." @default.
- W2108593463 created "2016-06-24" @default.
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- W2108593463 date "2013-02-28" @default.
- W2108593463 modified "2023-10-18" @default.
- W2108593463 title "Synthesis, Structural Characterisation and Stereochemical Investigation of Chiral Sulfur-Functionalised N-Heterocyclic Carbene Complexes of Palladium and Platinum" @default.
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- W2108593463 doi "https://doi.org/10.1002/chem.201204320" @default.
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