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- W2108606629 endingPage "694" @default.
- W2108606629 startingPage "688" @default.
- W2108606629 abstract "Abstract The synthesis, structure, and gas adsorption properties of three new metal–organic frameworks (MOFs) designed from isonicotinic acid (INA) and its fluorinated analogue 3‐fluoroisonicotinic acid (FINA) along with Co II as the metal center have been reported. Co‐INA‐1 ([Co 3 (INA) 4 (O)(C 2 H 5 OH) 3 ][NO 3 ] ⋅ C 2 H 5 OH ⋅ 3 H 2 O; INA=isonicotinic acid) and Co‐INA‐2 ([Co(INA) 2 ] ⋅ DMF) are structural isomers as are Co‐FINA‐1 ([Co 3 (FINA) 4 (O)(C 2 H 5 OH) 2 ] ⋅ H 2 O; FINA=3‐fluoroisonicotinic acid) and Co‐FINA‐2 ([Co(FINA) 2 ] ⋅ H 2 O), but the most important thing to note here is that Co‐INA‐1 and Co‐FINA‐1 are isostructural as are Co‐INA‐2 and Co‐FINA‐2. The effect of partial introduction of fluorine atoms into the framework on the gas uptake properties of MOFs having similar structures has been analyzed experimentally and computationally in isostructural MOFs." @default.
- W2108606629 created "2016-06-24" @default.
- W2108606629 creator A5003591630 @default.
- W2108606629 creator A5037939795 @default.
- W2108606629 creator A5057991087 @default.
- W2108606629 creator A5072476367 @default.
- W2108606629 date "2011-12-09" @default.
- W2108606629 modified "2023-10-18" @default.
- W2108606629 title "Fluorinated Metal-Organic Frameworks: Advantageous for Higher H2 and CO2 Adsorption or Not?" @default.
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