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- W2108642181 abstract "The catalytic asymmetric β-hydrogen transfer reduction of α-trifluoromethyl ketones using diethylzinc as the β-hydrogen donor was developed with the use of phosphinamide chiral ligand. The corresponding alcohol products were afforded in good yields with up to 73% ee. This method was successfully applied to the chemo- and enantioselective reduction of α-methyl/trifluoromethyl diketone, affording 88% yield and 70% ee of the fluorinated hydroxylketone product." @default.
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- W2108642181 date "2015-08-01" @default.
- W2108642181 modified "2023-09-26" @default.
- W2108642181 title "Catalytic asymmetric β-hydrogen transfer reduction of α-trifluoromethyl aromatic ketones with diethylzinc" @default.
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- W2108642181 doi "https://doi.org/10.1016/j.tetasy.2015.06.017" @default.
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