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• W2108643842 abstract "An enantio- and diastereoselective synthesis of syn-β-hydroxy-α-vinyl carboxylate esters 3 via the reductive aldol reaction of ethyl allenecarboxylate (2) with 10-trimethylsilyl-9-borabicyclo[3.3.2]decane (1R) has been developed. Density functional theory calculations suggest that the allene hydroboration involves the 1,4-reduction of 2 with the 1R, leading directly to dienolborinate Z-(O)-8a." @default.
• W2108643842 created "2016-06-24" @default.
• W2108643842 creator A5045681846 @default.
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• W2108643842 date "2013-10-18" @default.
• W2108643842 modified "2023-09-23" @default.
• W2108643842 title "Enantio- and Diastereoselective Synthesis of <i>syn</i>-β-Hydroxy-α-vinyl Carboxylic Esters via Reductive Aldol Reactions of Ethyl Allenecarboxylate with 10-TMS-9-Borabicyclo[3.3.2]decane and DFT Analysis of the Hydroboration Pathway" @default.
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• W2108643842 doi "https://doi.org/10.1021/ol4025277" @default.
• W2108643842 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3849616" @default.
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