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• W2108648087 abstract "Two dinuclear complexes, {[Cd(bdpp)Cl2](CH3OH)}2 (1) and [Cd(bdpp)(N3)(NO3)]2 (2), have been synthesized by reactions of bdpp with cadmium salts (bdpp = 1,3-bis(3′,5′-dimethylpyrazol-1′-yl)propane), and characterized by IR, element analysis, fluorescence properties and single crystal structural analysis. Cd in 1 has a trigonal bipyramidal coordination geometry and two such units form a dimer through two μ-Cl bridges. Each Cd in 2 has a distorted octahedral coordination geometry and two Cd units form a dimer through μ1,1-N3 bridges. The emission spectra show λem = 413 nm for 1 and λem = 338 nm for 2." @default.
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• W2108648087 date "2007-07-01" @default.
• W2108648087 modified "2023-09-27" @default.
• W2108648087 title "Two new dinuclear complexes with flexible bipyrazole ligand bridged via μ-Cl or μ_1,1-N₃" @default.
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• W2108648087 doi "https://doi.org/10.1080/00958970701396166" @default.
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