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• W2108669263 abstract "IR. and Raman spectra of LnONO3 (50–4,000 cm−1, LnLa, Gd, Eu, and Dy) are reported and discussed. The low frequency region of the spectra reflects the cubic structure of these compounds. The dimensions of the cubic unit cells determined by X-Ray powder diagrams are: 12.81 ± 0.05 Å for EuONO3, 12.69 ± 0.05 Å for GdONO3, and 12.67 ± 0.05 Å for DyONO3. The vibrational frequencies of the nitrato group are consistent with a bidentate nitrate of C2v symmetry. The synthesis of anhydrous Ln (NO3)3 (LnLa, Gd, Eu, and Dy) by dehydration of the corresponding penta- or hexahydrates is described. The IR. and Raman spectra (50-4,000 cm−1) are analysed. Splitting of the bands point to a complex structure of these compounds. All six vibrational modes of the nitrato group are observed and the data are again consistent with bidentate NO−3 moieties. Finally, an analytical control of the purity of Ln (NO3)3 is suggested." @default.
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• W2108669263 date "1978-03-08" @default.
• W2108669263 modified "2023-09-25" @default.
• W2108669263 title "Vibrational Spectra of Anhydrous Lanthanum, Europium, Gadolinium, and Dysprosium Nitrates and Oxinitrates" @default.
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• W2108669263 doi "https://doi.org/10.1002/hlca.19780610224" @default.
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