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- W2108685549 abstract "The reaction of two equivalents of LiC6H3-2,6-(C6H3-2,6-Pri2)2 with GeCl2·dioxane, SnCl2 or PbBr2 in a diethyl ether solution resulted in the isolation of the monomeric σ-bonded diaryl tetrylene series E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge (1), Sn (2), or Pb(3)). Compounds 1-3 are highly sterically congested blue crystalline solids, which possess V-shaped structures and wide interligand bond angles. The solid state structures of 1-3 were determined by single-crystal X-ray methods while their solution structures were investigated by UV spectroscopy and in the cases of 2 and 3, respectively, by 119Sn and 207Pb NMR spectroscopy. The series 1-3 constitutes the most sterically crowded examples of σ-bonded diorgano group 14 derivatives yet isolated and, in contrast to previously reported: ER2 species, the C-E-C angles increase with increasing atomic number." @default.
- W2108685549 created "2016-06-24" @default.
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- W2108685549 date "2006-05-01" @default.
- W2108685549 modified "2023-09-30" @default.
- W2108685549 title "Synthesis and Characterization of the Monomeric Sterically Encumbered Diaryls E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge, Sn, or Pb)" @default.
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- W2108685549 doi "https://doi.org/10.1002/zaac.200500532" @default.
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