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- W2108727700 endingPage "19473" @default.
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- W2108727700 abstract "Herein, we report the synthesis, separation and characterisation of the E- and Z-isomers of dipyrrolyldiphenylethene to study their emission behaviour in the aggregation state and solid state. The E-isomer showed pronounced aggregation induced emission (AIE) whereas the Z-isomer showed crystallization induced emission (CIE). The present study explains that the emission behaviour (AIE/CIE) is dependent on the inter/intra molecular interactions between the molecules. The study also confirms that restriction of intramolecular rotation (RIR) is the main cause of AIE/CIE in olefinic luminogens Tetraphenylethylene (TPE) type systems rather than E/Z isomerisation." @default.
- W2108727700 created "2016-06-24" @default.
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- W2108727700 date "2015-01-01" @default.
- W2108727700 modified "2023-09-27" @default.
- W2108727700 title "Stereochemical modulation of emission behaviour in E/Z isomers of diphenyldipyrroethene from aggregation induced emission to crystallization induced emission" @default.
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- W2108727700 doi "https://doi.org/10.1039/c5cp02400e" @default.
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