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- W2108760118 abstract "The electron impact induced retro Diels-Alder cleavage of 4-vinylcyclohexene, 1,4-dimethyl-4-vinylcyclo-hexene, limonene, dicyclopentadiene and dicyclohexadiene has been investigated using deuterium labelled analogues. With limonene, dicylopentadiene and dicyclohexadiene the charged diene fragments are produced with the same probability from both subunits of the molecular ion. With 4-vinylcyclohexene and 1,4-dimethyl-4-vinylcyclohexene, diene fragments containing the former vinyl group are charged preferentially. This small asymmetry of charge distribution was found to be independent of the ionizing energy. A new, qualitative rationalization is suggested to account for the unsymmetrical charge distribution in 4-vinylcyclohexene and 1,4-dimethyl-4-vinylcyclohexene. Metastable spectra and hydrogen scrambling are discussed." @default.
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- W2108760118 date "1980-01-01" @default.
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- W2108760118 title "Charge distribution between formally identical fragments: The retro Diels-Alder cleavage" @default.
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- W2108760118 doi "https://doi.org/10.1002/oms.1210150104" @default.
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