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• W2108834666 abstract "The uranium(IV) hexathiolate complexes [(thf)3Na(µ-SR)3U(µ-SR)3Na(thf)3](thf = tetrahydrofuran; R = Bun, Pri, But or Ph) were prepared by treatment of UCl4 or U(BH4)4 with the corresponding NaSR reagent. The crystal structures of the tert-butyl and phenyl derivatives have been determined. Reaction of U(SBun)4 with NaSBun gave the anion [U(SBun)6]2– which, by protonation with NEt3HBPh4, was transformed back into U(SBun)4." @default.
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• W2108834666 date "1993-01-01" @default.
• W2108834666 modified "2023-09-25" @default.
• W2108834666 title "Synthesis and crystal structure of the homoleptic uranium (<scp>IV</scp>) thiolates [(thf)₃Na(µ-SR)₃U(µ-SR)₃NA(thf)₃](thf = tetrahydrofuran; R = Bu^tor Ph)" @default.
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• W2108834666 doi "https://doi.org/10.1039/dt9930002251" @default.
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