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- W2108977225 abstract "Enynes substituted with a tertiary hydroxyl group attached to one of the alkyne units react with iodobenzenes in a Pd-catalyzed domino reaction. The cascade consists of an intermolecular anti-carbopalladation and a terminating Heck reaction. This process leads to arene-substituted dienes. One tetrasubstituted double bond is embedded in a six-membered ring system, and the other trisubstituted alkene is located in an exocyclic position. On treatment with acid, the emerging tertiary carbocation is attacked by the arene to give a five-membered ring, and thus results in the formation of alkylated indenes." @default.
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- W2108977225 date "2015-08-18" @default.
- W2108977225 modified "2023-10-07" @default.
- W2108977225 title "Access to Indene Derivatives by a Sequence of Intermolecular<i>anti</i>-Carbopalladation, Heck Reaction, and Electrophilic Attack" @default.
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- W2108977225 doi "https://doi.org/10.1002/ejoc.201500868" @default.
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