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• W2108992493 startingPage "3578" @default.
• W2108992493 abstract "Abstract Several N‐linked glycoproteins have been identified in archaea and there is growing evidence that the N‐glycan is involved in survival and functioning of archaea in extreme conditions. Chemical synthesis of the archaeal N‐glycans represents a crucial step towards understanding the putative function of protein glycosylation in archaea. Herein the first total synthesis of the archaeal L ‐asparagine linked hexasaccharide from Methanothermus fervidus is reported using a highly convergent [3+3] glycosylation approach in high overall yields. The synthesis relies on efficient preparation of regioselectively protected thioglycoside building blocks for orthogonal glycosylations and late stage N‐aspartylation." @default.
• W2108992493 created "2016-06-24" @default.
• W2108992493 creator A5042656179 @default.
• W2108992493 creator A5072293774 @default.
• W2108992493 date "2014-03-11" @default.
• W2108992493 modified "2023-10-18" @default.
• W2108992493 title "Chemical Synthesis of Asparagine-Linked Archaeal N-Glycan from<i>Methanothermus fervidus</i>" @default.
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• W2108992493 doi "https://doi.org/10.1002/chem.201304950" @default.
• W2108992493 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24616211" @default.
• W2108992493 hasPublicationYear "2014" @default.
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