FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2109014096> ?p ?o ?g. }

• W2109014096 endingPage "51" @default.
• W2109014096 startingPage "45" @default.
• W2109014096 abstract "A novel method for inductively coupled plasma atomic emission spectrometry (ICP-AES) determination of trace amounts of Pt(II), Pd(II) and Rh(III), based on gaseous compounds introduction into the plasma as their diethyldithiocarbamate complexes by electrothermal vaporization (ETV), was developed. At the temperature of 1100 °C, the trace amounts of Pt, Pd and Rh were vaporized into plasma. The factors affecting the formation of the chelates and their vaporization behaviors, such as ashing temperature and time, vaporization temperature and time, pH and the concentration of chelating reagents were studied in detail. Under the optimized conditions, the limits of detection (LODs) (3σ) of Pt, Pd and Rh for tested solutions were 5.4, 1.4 and 0.8 ng ml−1, and for actual sample (auto-catalyst NIST SRM 2557) were 0.27, 0.07 and 0.04 μg g−1, respectively. The relative standard deviations (RSDs) for Pt, Pd and Rh were 1.4, 2.6 and 2.4% (CPt=0.5 μg ml−1, CPd,Rh=0.25 μg ml−1, n=7), respectively. The linear ranges of calibration graphs for Pt, Pd and Rh cover three orders of magnitude. Compared with conventional electrothermal vaporization technique, using the reagent of diethyldithiocarbamate as chemical modifier could not only enhance the analytical sensitivities, but also reduce the vaporization temperature. By combination with a separation/preconcentration step, the proposed method had been successfully applied to the analysis of the artificial seawater, tap water and urine with recoveries ranging from 91 to 106%. The two certified reference material meager platinpalladium ore GBW 07293 and auto-catalyst NIST SRM 2557 was also analyzed for validation, and the determined values obtained were in good agreement with the certified values." @default.
• W2109014096 created "2016-06-24" @default.
• W2109014096 creator A5009236216 @default.
• W2109014096 creator A5014812552 @default.
• W2109014096 creator A5027225886 @default.
• W2109014096 creator A5065592688 @default.
• W2109014096 date "2004-05-01" @default.
• W2109014096 modified "2023-10-12" @default.
• W2109014096 title "Determination of platinum, palladium and rhodium in biological and environmental samples by low temperature electrothermal vaporization inductively coupled plasma atomic emission spectrometry with diethyldithiocarbamate as chemical modifier" @default.
• W2109014096 cites W1898425321 @default.
• W2109014096 cites W1982122960 @default.
• W2109014096 cites W1989682922 @default.
• W2109014096 cites W1990584480 @default.
• W2109014096 cites W1992346231 @default.
• W2109014096 cites W2003968287 @default.
• W2109014096 cites W2027699208 @default.
• W2109014096 cites W2028284929 @default.
• W2109014096 cites W2032123118 @default.
• W2109014096 cites W2042143095 @default.
• W2109014096 cites W2042963426 @default.
• W2109014096 cites W2056161334 @default.
• W2109014096 cites W2069411000 @default.
• W2109014096 cites W2069792776 @default.
• W2109014096 cites W2074928239 @default.
• W2109014096 cites W2077029424 @default.
• W2109014096 cites W2079275562 @default.
• W2109014096 cites W2079590758 @default.
• W2109014096 cites W2084959841 @default.
• W2109014096 cites W2091616431 @default.
• W2109014096 cites W2093351092 @default.
• W2109014096 cites W2127016166 @default.
• W2109014096 cites W2145955984 @default.
• W2109014096 cites W2156432092 @default.
• W2109014096 doi "https://doi.org/10.1016/j.aca.2003.12.055" @default.
• W2109014096 hasPublicationYear "2004" @default.
• W2109014096 type Work @default.
• W2109014096 sameAs 2109014096 @default.
• W2109014096 citedByCount "57" @default.
• W2109014096 countsByYear W21090140962012 @default.
• W2109014096 countsByYear W21090140962013 @default.
• W2109014096 countsByYear W21090140962014 @default.
• W2109014096 countsByYear W21090140962015 @default.
• W2109014096 countsByYear W21090140962016 @default.
• W2109014096 countsByYear W21090140962017 @default.
• W2109014096 countsByYear W21090140962019 @default.
• W2109014096 countsByYear W21090140962021 @default.
• W2109014096 countsByYear W21090140962022 @default.
• W2109014096 crossrefType "journal-article" @default.
• W2109014096 hasAuthorship W2109014096A5009236216 @default.
• W2109014096 hasAuthorship W2109014096A5014812552 @default.
• W2109014096 hasAuthorship W2109014096A5027225886 @default.
• W2109014096 hasAuthorship W2109014096A5065592688 @default.
• W2109014096 hasConcept C100859065 @default.
• W2109014096 hasConcept C113196181 @default.
• W2109014096 hasConcept C119128265 @default.
• W2109014096 hasConcept C121332964 @default.
• W2109014096 hasConcept C147789679 @default.
• W2109014096 hasConcept C161790260 @default.
• W2109014096 hasConcept C162356407 @default.
• W2109014096 hasConcept C165697059 @default.
• W2109014096 hasConcept C178790620 @default.
• W2109014096 hasConcept C185592680 @default.
• W2109014096 hasConcept C195801359 @default.
• W2109014096 hasConcept C40875361 @default.
• W2109014096 hasConcept C43617362 @default.
• W2109014096 hasConcept C502130503 @default.
• W2109014096 hasConcept C518104683 @default.
• W2109014096 hasConcept C521398313 @default.
• W2109014096 hasConcept C55493867 @default.
• W2109014096 hasConcept C62520636 @default.
• W2109014096 hasConcept C82706917 @default.
• W2109014096 hasConcept C95974651 @default.
• W2109014096 hasConcept C99293441 @default.
• W2109014096 hasConceptScore W2109014096C100859065 @default.
• W2109014096 hasConceptScore W2109014096C113196181 @default.
• W2109014096 hasConceptScore W2109014096C119128265 @default.
• W2109014096 hasConceptScore W2109014096C121332964 @default.
• W2109014096 hasConceptScore W2109014096C147789679 @default.
• W2109014096 hasConceptScore W2109014096C161790260 @default.
• W2109014096 hasConceptScore W2109014096C162356407 @default.
• W2109014096 hasConceptScore W2109014096C165697059 @default.
• W2109014096 hasConceptScore W2109014096C178790620 @default.
• W2109014096 hasConceptScore W2109014096C185592680 @default.
• W2109014096 hasConceptScore W2109014096C195801359 @default.
• W2109014096 hasConceptScore W2109014096C40875361 @default.
• W2109014096 hasConceptScore W2109014096C43617362 @default.
• W2109014096 hasConceptScore W2109014096C502130503 @default.
• W2109014096 hasConceptScore W2109014096C518104683 @default.
• W2109014096 hasConceptScore W2109014096C521398313 @default.
• W2109014096 hasConceptScore W2109014096C55493867 @default.
• W2109014096 hasConceptScore W2109014096C62520636 @default.
• W2109014096 hasConceptScore W2109014096C82706917 @default.
• W2109014096 hasConceptScore W2109014096C95974651 @default.
• W2109014096 hasConceptScore W2109014096C99293441 @default.
• W2109014096 hasIssue "1" @default.
• W2109014096 hasLocation W21090140961 @default.
• W2109014096 hasOpenAccess W2109014096 @default.
• W2109014096 hasPrimaryLocation W21090140961 @default.

• next