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- W2109036309 abstract "Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by N-methylvaline-derived Lewis-basic formamides 3a-d with high enantioselectivity (< or =95% ee) and low catalyst loading (1-5 mol %) at room temperature in toluene. Appending a fluorous tag, as in 5a-c, simplifies the isolation procedure, while preserving high enantioselectivity (< or =92% ee)." @default.
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- W2109036309 date "2007-01-18" @default.
- W2109036309 modified "2023-10-18" @default.
- W2109036309 title "Organocatalysis with a Fluorous Tag: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by Amino Acid-Derived Formamides" @default.
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- W2109036309 doi "https://doi.org/10.1021/jo062215i" @default.
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