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- W2109091147 abstract "Base hydrolysis and cyclohepta-amylose-catalysed hydrolysis of 2-oxo-4,4,5,5-tetramethylimidazolidin-1-oxyl (1), its thiocarbonyl analogue (6), the carbamoyl nitroxides (7a–c), and the ester nitroxide (8) were studied by e.s.r. spectroscopy. On base hydrolysis in the absence of cyclohepta-amylose, the intermediate radical anions RN(–O˙)CO2–(R = But and NH2CMe2CMe2–) were detected before decarboxylation. Hydrolysis of the amide group of the carbamoyl nitroxides is faster than that of 4,4,5,5- tetramethylimidazolidin-2-one (9) and therefore there is activation by the nitroxide group. For rate-determining nucleophilic addition to the carbonyl group, values of ke.s.r. correlate inversely with aN– 1 values, and this is explained in terms of the predominant activating inductive effect of the nitroxide group. When the ester (8) reacted, the carbonyl nitroxide group was hydrolysed before the ester group. Complexing of the compounds (1), (6), (7a–c), and (8) with cyclohepta-amylose caused anisotropic effects in the e.s.r. spectra, reduced aN– 1 values, and increased rates of hydrolysis. These effects were greatest for carbamoyl nitroxide (1). In the cyclohepta-amylose-catalysed reaction, cycloamylose alkoxide ion acts as nucleophile but no intermediates are detected since both bonds of the carbamoyl and ester nitroxide systems are rapidly hydrolysed." @default.
- W2109091147 created "2016-06-24" @default.
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- W2109091147 date "1985-01-01" @default.
- W2109091147 modified "2023-09-25" @default.
- W2109091147 title "Cyclohepta-amylose-catalysed hydrolysis of 2-oxo-4,4,5,5-tetramethylimidazolidin-1-oxyl and of related carbamoyl and ester nitroxides. Nitroxide as spin label and activating group" @default.
- W2109091147 doi "https://doi.org/10.1039/p29850001313" @default.
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