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- W2109093403 abstract "The crystallographic and magnetic nature of ZrMnSi, ZrMnGe, and HfMnGe is studied by X-ray, neutron diffraction, and magnetometric methods. All three compounds crystallize in the TiNiSi-type structure. Unit cell parameters and atomic positional parameters are determined from X-ray and neutron diffraction data obtained at room temperature. Susceptibility measurements indicate that the samples are paramagnetic between 80 and 600 K and the Curie-Weiss law is obeyed. The observed value of paramagnetic moment localized on Mn atom is discussed in terms of Pauling valence concept. Mittels Röntgen- und Neutronenbeugung sowie magnetometrischen Methoden wird das kristallo-graphische und magnetische Verhalten von ZrMnSi, ZrMnGe und HfMnGe untersucht. Alle drei Verbindungen kristallisieren in der TiNiSi-Struktur. Die Parameter der Einheitszelle und atomaren Anordnung werden aus bei Zimmertemperatur erhaltenen Röntgen- und Neutronenbeugungsdaten bestimmt. Suszeptibilitätsmessungen zeigen, daß die Proben zwischen 80 und 600 K. paramagnetisch sind und das Curie-Weiß-Gesetz befolgen. Der beobachtete Wert des am Mn-Atom lokalisierten paramagnetischen Moments wird mit dem Paulingschen Valenzkonzept diskutiert." @default.
- W2109093403 created "2016-06-24" @default.
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- W2109093403 date "1986-03-16" @default.
- W2109093403 modified "2023-10-13" @default.
- W2109093403 title "Magnetic Properties of ZrMnSi, ZrMnGe, and HfMnSi Intermetallics" @default.
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- W2109093403 doi "https://doi.org/10.1002/pssa.2210940124" @default.
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