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• W2109116115 abstract "Herein we report a protocol for the enantioselective synthesis of the three stereoisomers of 1,1′-(1,1′-binaphthalene-2,2′-diyl)bis(2,2,2-trifluoroethanol) and their characterization. These compounds, that combine axial and central chirality, might present interesting properties for enantiorecognition. Different reduction processes were applied to racemic and enantiopure 1,1′-(1,1′-binaphthalene-2,2′-diyl)bis(2,2,2-trifluoroethanone) allowing the isolation of the corresponding ketols, 2,2,2-trifluoro-1-[2′-(2,2,2-trifluoro-1-hydroxyethyl)-1,1′-binaphthalen-2-yl]ethanone, and the named diols." @default.
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• W2109116115 date "2012-11-01" @default.
• W2109116115 modified "2023-09-24" @default.
• W2109116115 title "New C2-symmetry diols accumulating one stereogenic axis and two stereogenic centers" @default.
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• W2109116115 doi "https://doi.org/10.1016/j.tet.2012.09.061" @default.
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