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- W21091175 abstract "The Gd3+ could play an intermediate role in energy transfer to produce light, while the Sb3+ promisingly served as a sensitizer or an activator in luminescence since its ns2–nsnp transition having a large cross section to capture excitation energy. In this work, the energy transfer between Gd3+ and Sb3+ in YBO3 host was studied. The phosphors were synthesized with a solid-state reaction method, and their crystal structure was examined with the X-ray diffraction analysis. The dependence of energy transfer on the distance between Gd3+ was revealed by changing Gd3+ and Sb3+ concentrations, respectively. The results revealed that excitation energy was transferred from Gd3+ towards Sb3+, which was contrary to the Bi3+→Gd3+ energy transfer that was previously reported in YBO3, although both Sb3+ and Bi3+ have the same ns2 electronic configuration. Moreover, the excitation energy would transfer among different Gd3+ ions via sublattice until trapped by Sb3+." @default.
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- W21091175 date "2013-11-01" @default.
- W21091175 modified "2023-10-17" @default.
- W21091175 title "Luminescence and energy transfer in the Sb3+ and Gd3+ activated YBO3 phosphor" @default.
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- W21091175 doi "https://doi.org/10.1016/j.jlumin.2013.06.014" @default.
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