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• W2109126875 abstract "Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate Bi3Mn4O12(NO3) (space group P3, a = 4.9692(1) Å, c = 13.1627(3) Å) prepared by hydrothermal synthesis is of a new structural type including flat NO3 layers alternating with blocks of two PbSb2O6-like layers. Mn4+ (S = 3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of −257 K, no long-range ordering was observed down to 0.4 K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions." @default.
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• W2109126875 date "2009-05-15" @default.
• W2109126875 modified "2023-10-03" @default.
• W2109126875 title "Synthesis, Crystal Structure, and Magnetic Properties of Bi₃Mn₄O₁₂(NO₃) Oxynitrate Comprising <i>S</i> = 3/2 Honeycomb Lattice" @default.
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• W2109126875 doi "https://doi.org/10.1021/ja901922p" @default.
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