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• W2109127966 startingPage "730" @default.
• W2109127966 abstract "The syntheses of the novel acyclic nucleosides 5a–5m, carrying different N-[(benzyloxy)(aryl)methyl] substituents, are described (Scheme). These compounds could be prepared in medium-to-good yields by either direct or silyl-assisted coupling of the electrophiles 6 with either purine or pyrimidine nucleobases, or with different imidazole derivatives. The reactivity of the positively charged electrophilic intermediates derived from 6 upon Cl− abstraction was rationalized by ab initio HF/6-311G quantum-mechanic calculations. The positive charge was found to be dispersed differently, depending on the electronic properties of the aryl substituents." @default.
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• W2109127966 date "2007-04-01" @default.
• W2109127966 modified "2023-10-17" @default.
• W2109127966 title "Synthesis of Acyclic Nucleosides withN-[(Benzyloxy)(aryl)methyl] Substituents as Potential HEPT, EBPU, and TNK-651 Analogues" @default.
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• W2109127966 doi "https://doi.org/10.1002/hlca.200790073" @default.
• W2109127966 hasPublicationYear "2007" @default.
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