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- W2109143917 abstract "We have measured the constant-pressure heat capacity Cp of pure monoclinic ZrO2 between 2.75 and 350 K. At low temperatures we find heat capacity in excess of the thermal acoustic phonon contribution, which we attribute to the ingress of low-lying optic mode vibrations. We have calculated the heat capacity at constant volume Cv at the high-temperature end of our measurement range and used these values with the harmonic model to derive the moments of the phonon spectrum. Comparing the moments of the monoclinic phase with theoretically derived corresponding moments for the tetragonal phase, we find that a downward shift of optic mode frequencies accompanies the tetragonal-to-monoclinic transformation." @default.
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- W2109143917 date "1990-08-01" @default.
- W2109143917 modified "2023-10-17" @default.
- W2109143917 title "Heat Capacity of Monoclinic Zirconia between 2.75 and 350 K" @default.
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- W2109143917 doi "https://doi.org/10.1111/j.1151-2916.1990.tb07619.x" @default.
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