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- W2109146303 abstract "The reflection spectra of α, β and γ MnS have been recorded in the region 12,000 to 40,000 cm−1, together with a range of solid solutions of MnS in hexagonal ZnS. This work was carried out at room and low temperature. Assignments are given for the observed transitions within the 3 d5 configuration of the Mn2+ ion. The relation between the crystal field parameter, 10 Dq, in the different crystal forms is discussed and shown to be in agreement with basic ligand field theory. Die Remissionsspektren von α-, β- und γ-MnS sowie fester Lösungen von MnS in hexagonalem ZnS wurden im Bereich 12000 bis 40000 cm−1 bei Raumtemperatur und 77°K aufgenommen. Für die beobachteten Übergänge innerhalb der 3 d5-Konfiguration des Mn2+-Ions werden Zuordnungen angegeben. Die Beziehung zwischen dem Kristallfeldparameter 10 Dq in den verschiedenen Kristallformen wird diskutiert, und es wird gezeigt, daß dieser mit der zugrunde gelegten Ligandenfeldtheorie in Übereinstimmung steht." @default.
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- W2109146303 date "1963-07-01" @default.
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- W2109146303 title "The Electronic States of Octahedral and Tetrahedral Mn<sup>++</sup>in α, β and γ Manganous Sulphide" @default.
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- W2109146303 doi "https://doi.org/10.1002/bbpc.19630670503" @default.
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